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Creators/Authors contains: "TenHoeve, Tyler M."

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  1. ; ; ; ; ; ; ; ; ; ; et al (, Organic & Biomolecular Chemistry)
    Novel tungstenooxaziridine complex promotes the oxyamination of substituted alkenes with high stereoselectivity and stereospecificity. Mechanistic studies provide evidence for a highly selectivesyn-difunctionalization pathway. 
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  2. ; ; ; ; ; ; ; (, Chemical Communications)
    Herein we report the zirconooxaziridine promoted aziridination of alkenes using chloramine T as the quantitative source of N. The reaction works with high yields, diastereoselectivities and stereospecificity for a wide variety of substituted alkenes. A potential mechanism involving the formation of a zirconooxaziridine complex as the active catalyst has been proposed and initial mechanistic data would indicate that a highly associative mechanism is the predominant pathway for this transformation. 
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